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Creators/Authors contains: "Dubrovina, Anastasiia"

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  1. ; ; ; (, Angewandte Chemie International Edition)
    Abstract A mild visible light‐induced palladium‐catalyzed alkyl Heck reaction of diazo compounds andN‐tosylhydrazones is reported. A broad range of vinyl arenes and heteroarenes with high functional group tolerance, as well as a range of different diazo compounds, can efficiently undergo this transformation. This method features Brønsted acid‐assisted generation of hybrid palladium C(sp3)‐centered radical intermediate, which allowed for new selective C−H functionalization protocol. 
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